Mechanisms of Proton Conductance in Polymer Electrolyte Membranes
نویسندگان
چکیده
منابع مشابه
Recent developments in high-temperature proton conducting polymer electrolyte membranes
Progress in the area of proton conducting polymer electrolyte membranes is intimately linked with the development of polymer electrolyte membrane fuel cells, and is today largely driven by the insufficient properties of humidified Nafion membranes at temperatures above 100 8C. Recent developments in the field include new ionomers and hybrid membranes containing inorganic nanoparticles to contro...
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We report 1H-1,2,3-triazole as an active group to dramatically enhance proton conduction in a polymer electrolyte membrane (PEM). The conductivities of a poly(4-vinyl-1H-1,2,3-triazole) membrane without any acidic dopants are about 105 times greater than those of poly(4-vinylimidazole) in dry air at 50-150 degrees C. Polymers with groups promoting proton conduction attached to the backbone have...
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Water-fed photo-electrolysis cells equipped with perfluorosulfonic acid (Nafion® 115) and quaternary ammonium-based (Fumatech® FAA3) ion exchange membranes as separator for hydrogen and oxygen evolution reactions were investigated. Protonic or anionic ionomer dispersions were deposited on the electrodes to extend the interface with the electrolyte. The photo-anode consisted of a large band-gap ...
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Proton exchange fuel cells (PEFCs) have the potential to provide power for a variety of applications ranging from electronic devices to transportation vehicles. A major challenge towards economically viable PEFCs is finding an electrolyte that is both durable and easily passes protons. In this article, we study novel anhydrous proton-conducting membranes, formed by incorporating ionic liquids i...
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ژورنال
عنوان ژورنال: The Journal of Physical Chemistry B
سال: 2001
ISSN: 1520-6106,1520-5207
DOI: 10.1021/jp003182s